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Bismuth Triflate-Catalyzed Mild and Efficient Epoxide Opening by Aromatic Amines under Aqueous Conditions.

โœ Scribed by Thierry Ollevier; Guillaume Lavie-Compin

Book ID
101958021
Publisher
John Wiley and Sons
Year
2004
Weight
78 KB
Volume
35
Category
Article
ISSN
0931-7597

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An efficient method for the ring opening
An efficient method for the ring opening of epoxides with aromatic amines catalyzed by bismuth trichloride
โœ Thierry Ollevier; Guillaume Lavie-Compin ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 74 KB

We describe here the nucleophilic opening of epoxides with aromatic amines in the presence of a catalytic amount of BiCl 3 . The mild reaction conditions and the low toxicity of bismuth salts make this procedure particularly attractive for the synthesis of b-amino alcohols.