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Bismuth Compounds in Organic Synthesis. A One-Pot Synthesis of Homoallyl Ethers and Homoallyl Acetates from Aldehydes Catalyzed by Bismuth Triflate

โœ Scribed by Anzalone, Peter W.; Baru, Ashvin R.; Danielson, Eric M.; Hayes, Patrick D.; Nguyen, Mai P.; Panico, Ambrose F.; Smith, Russell C.; Mohan, Ram S.


Book ID
125960870
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
152 KB
Volume
70
Category
Article
ISSN
0022-3263

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Bismuth triflate catalyzed allylation of
โœ Laura C. Wieland; Herbert M. Zerth; Ram S. Mohan ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 439 KB

The allylation of acetals using allyltrimethylsilane is efficiently catalyzed by bismuth triflate (1.0 mol%). The reaction proceeds smoothly at room temperature to afford the corresponding homoallyl ether in good yield. The mild reaction conditions, the low toxicity of bismuth salts, and the high ca