Bis(hexaethylpararosanilinium) hexamolybdate
✍ Scribed by Deng, Xiao-Tao ;Wang, Xiao-Yan ;Wang, Cheng-Gang
- Book ID
- 104487313
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 215 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The title compound, (C 31 H 42 N 3 ) 2 [Mo 6 O 19 ], contains an [Mo 6 O 19 ] 2À hexamolybdate anion, which is built up from six distorted MoO 6 octahedra sharing common edges and one common vertex at the central O atom, and two hexaethylpararosaniline cations to balance the charge. The Mo-O distances lie in the range 1.670 (3)-2.325 (2) A ˚.
📜 SIMILAR VOLUMES
The title compound, {(C 6 H 7 N 2 O) 2 (H 3 O)[NaMo 8 O 26 ]Á5H 2 O} n , features centrosymmetric oxomolybdate anions [Mo 8 O 26 ] 4À (site symmetry 1). These are linked by Na + cations (site symmetry 1), yielding chains which are connected by hydrogen bonds into a three-dimensional network.
Single-crystal X-ray study T = 293 K Mean '(Ni±O) = 0.002 A Ê R factor = 0.031 wR factor = 0.089 Data-to-parameter ratio = 11.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.