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Bis{(E)-2-[2-(2-hydroxybenzoyl)hydrazono]propanoato-κ3O,N,O′}copper(II) trihydrate

✍ Scribed by Liu, Feng ;Wu, Wang-Ting ;Zhang, Wei-Ping ;Chen, Feng-Ying ;He, Shui-Yang

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 895 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680704072x

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✦ Synopsis

The title compound, [Cu(C 10 H 9 N 2 O 4 ) 2 ]Á3H 2 O, was obtained by evaporation of an aqueous ethanol solution of 2-[2-(2hydroxybenzoyl)hydrazono]propanoic acid and cupric chloride. Each Cu II atom is six-coordinated in a distorted octahedral geometry by carboxylate and acyl O atoms and imide N atoms from two tridentate ligands in the keto form, forming two five-membered rings sharing one edge for each ligand. N-HÁ Á ÁO and O-HÁ Á ÁO hydrogen bonds between water molecules and the ligands result in the formation of a three-dimensional network.

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