New nickel(II) complexes of the hexadentate macrobicycles 6-(2-aminoethyl)-1, 3,6,9,11,14-hexaazabicyclo[12.3.1] 3,6,9,11,14-hexaazabicyclo[12.2.1]heptadecane (2), and 6-(2-aminoethyl)-1, 3,6,9,11,15-hexaazabicyclo[13.3.1]nonadecane (3) have been prepared selectively by the metal template condensati
Bis(diorganylphosphinodithioformato-S,P)nickel(II)Complexes—Novel Four-Membered Ring Chelates
✍ Scribed by Dr. Jürgen Kopf; Dr. Rudolf Lenck; Dr. Sigurjon N. Olafsson; Dr. Reinhard Kramolowsky
- Book ID
- 101550224
- Publisher
- John Wiley and Sons
- Year
- 1976
- Tongue
- English
- Weight
- 219 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
161
The "C-NMR spectra were recorded at 25.2 MHz. Chemical shifts relative to TMS. multiplicities characterized by off-resonance procedure as d =doublet and t=triplet.
[7] We have also prepared isoelectronic complexes of iron by the same method, and are investigating further compounds of this type formed by other transition metals.
📜 SIMILAR VOLUMES
## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_