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Bis­(diiso­propyl­ammonium) sulfate

✍ Scribed by Reiß, Guido J. ;Engel, Judith S.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
338 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

Bis(diisopropylammonium) sulfate, 2C 6 H 16 N + ÁSO 4 2À , crystallizes in the monoclinic centrosymmetric space group P2 1 /n. The asymmetric unit contains two crystallographically independent diisopropylammonium cations and one sulfate anion in general positions. Strong hydrogen bonding occurs between the cations and anions, forming layers parallel to (101). Each layer is composed of ring systems that can be classi®ed according to Etter's nomenclature as R 4 4 (12) and R 12 12 (36). IR and Raman spectroscopy con®rm the presence of a nearly undistorted sulfate anion.

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