Biscyclopropanation of C70
β Scribed by Bingel, Carsten ;Schiffer, Heinz
- Publisher
- John Wiley and Sons
- Year
- 1995
- Tongue
- English
- Weight
- 279 KB
- Volume
- 1995
- Category
- Article
- ISSN
- 0947-3440
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β¦ Synopsis
Abstract
The biscyclopropanation of C~70~ with bromomalonate anions shows a strong preference for three regioisomers, which can be separated by column chromatography. The structures of the three regioisomers were determined by ^13^CβNMR spectroscopy. The two cyclopropanation reactions take place on opposite hemispheres of C~70~.
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