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Bis(cis-cyclo­hexano-12-crown-4)­potassium chloro­chromate

✍ Scribed by Kotlyar, Sergey A. ;Zubatyuk, Roman I. ;Shishkin, Oleg V. ;Chuprin, Gennady N. ;Kiriyak, Andrey V. ;Kamalov, Gerbert L.


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
438 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


metal-organic papers m908 Sergey A. Kotlyar et al. [K(C 24 H 44 O 8 )][CrClO 3 ] Acta Cryst. (2004). E60, m907±m909


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Isomeric cis-cyclohexano-13-crown-4 ethe
✍ G. W. Buchanan; M. Gerzain; R. C. Laister 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 443 KB 👁 1 views

The two positionally isomeric cyclohexanotetraoxacyclotridecanes (13-crown-4 ethers) were synthesized and studied via low-temperature NMR methods. For the 1,4,8,11-tetraoxa isomer, the cyclohexane ring inversion is a degenerate process, whereas for the 1,4,7,11-tetraoxa isomer, a preference of 1.4 k