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Bis(azidomethyl) oxetane/hydroxyl-terminated polybutadiene/bis(azidomethyl) oxetane triblock copolymer: Synthesis and characterization

✍ Scribed by T. S. Reddy; J. K. Nair; R. S. Satpute; R. M. Wagh; A. K. Sikder; S. Venugopalan


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
228 KB
Volume
106
Category
Article
ISSN
0021-8995

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✍ Jean-Jacques Jutier; AnΓ©mone De Gunzbourg; Robert E. Prud'homme πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 217 KB

The quasi-living cationic copolymerization of 3,3-bis(chloromethyl)oxetane (BCMO) and -caprolactone (-CL), using boron trifluoride etherate as catalyst and 1,4-butanediol as coinitiator, was investigated in methylene chloride at 0Β°C. The resulting hydroxyl-ended copolymers exhibit a narrow molecular