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Bis(arene) complexes of RuII. Synthesis, crystal structure and electrochemical behavior of [bis(η6-p-isopropyltoluene)Ru][BF4]2

✍ Scribed by Sandhya Suravajjala; Jayapal Reddy Polam; Leigh Christopher Porter

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
563 KB
Volume
461
Category
Article
ISSN
0022-328X

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## Abstract Reactions of the molybdates Na~2~MoO~4~⋅2 H~2~O and (__n__Bu~4~N)~2~[Mo~2~O~7~] with [{Ru(arene)Cl~2~}~2~] (arene=C~6~H~5~CH~3~, 1,3,5‐C~6~H~3~(CH~3~)~3~, 1,2,4,5‐C~6~H~2~(CH~3~)~4~) in water or organic solvents led to formation of the triple‐cubane organometallic oxides [{Ru(η^6^‐arene