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Bisannelation with a benzo[1,2-c:4,5-c']difuran equivalent: a new route to linear acene derivatives

โœ Scribed by Luo, Jihmei; Hart, Harold


Book ID
126417034
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
351 KB
Volume
53
Category
Article
ISSN
0022-3263

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A novel Cโ€“N cleavage in isoquinolines al
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Treatment of N-carbethoxy-1-benzylideneisoquinolines with LDA gives N-ethoxycarbonyl-1-amino-1-(2-vinylphenyl)-2-phenylethylenes, which can easily be transformed into N-carbethoxy-1-amino-2-phenylnaphthalenes. BichlerยฑNapieralski reaction of these latter compounds aords the corresponding benzo[c]phe