𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(4,4′-dimethyl-2,2′-bipyridine) ruthenium (II) Complexes Containing 2-Arylimidazo- [4,5-f] [1,10] phenanthroline: Syntheses, Characterization and Third-order Nonlinear Optical Properties

✍ Scribed by Hui Chao; Run-Hua Li; Qi-Wen Huang; Liang-Nian Ji

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
441 KB
Volume
20
Category
Article
ISSN
0256-7660

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Four novel mononuclear ruthenium(II) complexes [Ru(dmb)~2~L]^2+^ [dmb = 4,4′‐dimethyl‐2,2′‐bipyridine, L = imidazo‐[4,5‐f][1,10]phenanthroline (IP), 2‐phenylimidazo‐[4,5‐f][1,10]phenanthroline (PIP), 2‐(4′‐hydroxyphenyl)imidazo‐[4,5‐f] [1,10] phenanthroline (HOP), 2‐(4′‐dimethylaminophenyl) imidazo‐[4, 5‐f] [1,10] phenanthroline (DMNP)] were synthesized and characterized by ES‐MS, ^1^H NMR, UV‐vis and electrochemistry. The nonlinear optical properties of the ruthenium(II) complexes were investigated by Z‐scan techniques with 12 ns laser pulse at 540 nm, and all of them exhibit both nonlinear optical (NLO) absorption and self‐defocusing effect. The corresponding effective NLO susceptibility |x^3^| of the complexes is in the range of 2.68 × 10^−12^‐4.57 × 10^−12^ esu.

📜 SIMILAR VOLUMES

Preparation, physicochemical and third o
Preparation, physicochemical and third order nonlinear optical properties of bis(tetrabutylammonium)bis(2-thioxo-1,3-dithiole-4,5-dithiolato)mercurate(II)
✍ X. Q. Wang; Q. Ren; J. Sun; H. L. Yang; T. B. Li; H. L. Fan; G. H. Zhang; D. Xu; 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 347 KB

## Abstract Bis(tetrabutylammonium)bis(2‐thioxo‐1,3‐dithiole‐4,5‐dithiolato)mercurate(II) was prepared and characterized by elemental analyses, electronic absorption, infrared and X‐ray powder diffraction spectroscopy. The specific heat of the crystal was measured to be 1878.2 J.mol^–1^K^–1^ at 300

Synthesis, crystal structure and third o
Synthesis, crystal structure and third order nonlinear optical properties of bis(tetra-n-propylammonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)
✍ W. F. Guo; X. B. Sun; J. Sun; W. T. Yu; X. Q. Wang; G. H. Zhang; D. Xu 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 239 KB

A novel bis (dmit) complex of copper (II), [(C 3 H 7 ) 4 N] 2 [Cu(dmit) 2 ] (1), where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, was prepared and structurally characterized by X-ray single crystal diffraction. The copper (II) atom is tetracoordinated by four dmit S atoms, forming a nearly square