Bis(4-pyridyl)ditelluride as starting material for the synthesis of zwitterionic compounds and metal complexes
โ Scribed by Sailer S. dos Santos; Bruno N. Cabral; Ulrich Abram; Ernesto S. Lang
- Book ID
- 119305547
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 626 KB
- Volume
- 723
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Reaction of [Cpะ 2 NbH 3 ] (Cpะ = tBuC 5 H 4 ) with Te powder in THF gives [Cpะ 2 Nb(Te 2 )H] (1) and [Cpะ 6 Nb 4 Te 4 O] (2). The yield of 1 varies between 10 and 81% depending on the degree of oxygen contamination of the reagents. Complexes 1 and 2 react with [Cr(CO) 5 THF] to give [Cpะ 2 Nb-(Te 2
One-electron oxidation of the bis(ethene)manganacyclopentane 8a affords the manganaspironane 7a. Thus the ring closure of the two coordinated ethene molecules with the manganese atom is oxidatively induced.