Bis{4-bromo-2-[3-(cyclohexylamino)propyliminomethyl]phenolato}dithiocyanatonickel(II)
✍ Scribed by Su, Yong-Qing ;Wang, Ping ;He, Yong-Fu ;Liu, Li-Mei
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 239 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the mononuclear title compound, [Zn(C 13 H 15 BrNO) 2 ], the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands.
In the title mononuclear nickel(II) complex, [Ni(C 14 H 18 -NO 2 ) 2 ], the Ni II atom is four-coordinated in a square-planar geometry by two phenolate O atoms and two imine N atoms from two Schiff base ligands. The Ni atom lies on a centre of inversion. ## metal-organic papers Acta Cryst. (2006)
The title compound, [Zn(C~11~H~15~BrN~2~O)~2~](NO~3~)~2~, is a centrosymmetric mononuclear Schiff base zinc(II) complex. The Zn^II^ atom, lying on a twofold rotation axis, is four-coordinated by two phenolate O atoms and two imine N atoms from two Schiff base ligands, forming a tetrahedral coordinat
Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.007 A Ê R factor = 0.045 wR factor = 0.145 Data-to-parameter ratio = 14.8 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.