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[Bis(3-mesitylpyrazol-1-yl)(5-mesitylpyrazol-1-yl)borohydrido]dichloro­(2,4,6-tri-tert-butyl­phenolato)titanium toluene solvate

✍ Scribed by Michiue, Kenji ;Steele, Ian M. ;Jordan, Richard F.

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
172 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 200 K Mean (C-C) = 0.007 A R factor = 0.071 wR factor = 0.162 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

📜 SIMILAR VOLUMES

[Bis(3-mesitylpyrazol-1-yl)(5-mesitylpyr
[Bis(3-mesitylpyrazol-1-yl)(5-mesitylpyrazol-1-yl)borohydrido]dichloro­(5-mesitylpyrazole)titanium(III) toluene solvate
✍ Michiue, Kenji ;Steele, Ian M. ;Jordan, Richard F. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 141 KB

In the title Ti III complex, [Ti(C 36 H 40 BN 6 )Cl 2 (C 12 H 14 N 2 )]Á-C 7 H 8 , the Ti atom is coordinated in a distorted octahedral geometry by three N atoms that are constrained to a facial arrangement by the Tp Ms\* ligand [Tp Ms\* = HB(3-mesitylpyrazolyl) 2 (5-mesitylpyrazolyl)], by two mutua

2,6-Di-tert-butyl-4-{[N-(4,6-dichloro-1,
2,6-Di-tert-butyl-4-{[N-(4,6-dichloro-1,3,5-triazin-2-­yl)propyl­amino]meth­yl}phenol
✍ Zeng, Tao ;Chen, Li-Gong 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 152 KB

The title compound, C~21~H~30~Cl~2~N~4~O, contains a sterically hindered phenol group. The dihedral angle between the two rings is 72.3 (1)°. The propyl chain is disordered over two orientations.