The title compound, [Mn~2~(N~3~)~4~(C~14~H~17~N~3~)~2~], comprises two [Mn(bpea)(N~3~)]^+^ fragments [where bpea is the tridentate ligand __N__,__N__-bis(2-pyridylmethyl)ethylamine] bridged by two azide anions to form a centrosymmetric dinuclear complex. The coordination environment around the Mn^II
[Bis(3-aminopropyl-κN)(2-furylmethyl)amine-κN]dichloridocopper(II)
✍ Scribed by Wang, Peng ;Wang, Xiao-Hui ;Liu, Huan ;Zhou, Hong ;Pan, Zhi-Quan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 388 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
In the title complex, [CuCl 2 (C 11 H 21 N 3 O)], the five-coordinate Cu atom has a distorted square-pyramidal configuration. The crystal packing is stabilized by intermolecular N-HÁ Á ÁCl hydrogen-bonding interactions. The furan ring is disordered over two position, with site occupancy factors of ca. 0.6 and 0.4.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 102 K Mean '(C±C) = 0.005 A Ê Disorder in main residue R factor = 0.073 wR factor = 0.150 Data-to-parameter ratio = 17.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.038 wR factor = 0.099 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Di-l-chlorido-1:2j 2 Cl,2:3j 2 Cl-tetrachlorido-1jCl,2j 2 Cl,3jCl-bis[N,N 0 0 00 0 0bis(2-furylmethylene)diethylenetriamine]-1j 3 N,N 0 0 0 ,N 0 0 00 0 0 ;3j 3 N,N 0 0 0 ,N 0 0 00 0 0tricopper(II)