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Bis{2,2′-[ethane-1,2-diylbis(iminomethylene)]diphenolato-κ2O,N,N′,O′}cerium(IV) chloroform solvate

✍ Scribed by Yang, Shu-Ping ;Han, Li-Jun ;Wang, Da-Qi ;Wang, Bo

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 436 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680705101x

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✦ Synopsis

In the title compound, [Ce(C~16~H~18~N~2~O~2~)~2~]·CHCl~3~, the Ce^IV^ atom has an eight-coordinate geometry involving two tetradentate N,N′-(2-oxidobenzyl)ethane-1,2-diamine ligands. The asymmetric unit contains one molecule of the title complex and one chloroform molecule, linked by C—H...O and N—H...Cl hydrogen bonds. These neighbouring molecules are connected by two C—H...π interactions, and by N—H...Cl and C—H...Cl interactions, resulting in a three-dimensional network.

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