𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(2-guanidinobenzimidazole-κ2N,N′)copper(II) bis­(dicyanamide)

✍ Scribed by Zheng, Lei ;Zhang, Jia ;Yu, Ming-Ming ;Ni, Zhong-Hai ;Kou, Hui-Zhong

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
211 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

In the title compound, [Cu(C 8 H 9 N 5 ) 2 ](C 2 N 3 ) 2 , the Cu complex cation and dicyanamide anions lie on a twofold axis. Discounting the weak coordination of a dicyanamide anion, the Cu II atom is coordinated by four N atoms from two 2guanidinobenzimidazole ligands in a tetrahedrally distorted square-planar geometry. The cations and anions are linked via N-HÁ Á ÁN hydrogen bonds, forming a two-dimensional network parallel to (010). metal-organic papers m2472 Zheng et al. [Cu(C 8 H 9 N 5 ) 2 ](C 2 N 3 ) 2

📜 SIMILAR VOLUMES

Bis(biguanido-κ2N,N′)copper(II) dihydrat
Bis(biguanido-κ2N,N′)copper(II) dihydrate
✍ Su, Ying-Lan ;Lu, Li-Ping ;Li, Xue-Mei ;Zhu, Miao-Li 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 305 KB
Bis(μ-5-phenyl­tetrazolate-κ2N2:N3)­bis­
Bis(μ-5-phenyl­tetrazolate-κ2N2:N3)­bis­[(2,2′-bi­pyridine-κ2N,N′)­bis(5-phenyl­tetrazolate-κN2)copper(II)]
✍ Shao, Ze-Huai ;Luo, Jun ;Cai, Rui-Fang ;Zhou, Xi-Geng ;Weng, Lin-Hong ;Chen, Zhe 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê R factor = 0.052 wR factor = 0.118 Data-to-parameter ratio = 12.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis(μ-4-sulfobenzoato-κ2O:O′)­bis­[aqua(
Bis(μ-4-sulfobenzoato-κ2O:O′)­bis­[aqua(2,2′-bi­pyridine-κ2N,N′)copper(II)]
✍ Fan, Sai-Rong ;Xiao, Hong-Ping ;Zhang, Li-Ping ;Zhu, Long-Guan 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 243 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.004 A Ê R factor = 0.032 wR factor = 0.089 Data-to-parameter ratio = 12.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.