Bis(1,4,7-trithiacyclononane-κ3S,S′,S′′)iron(II) bis(perchlorate)
✍ Scribed by Green, Tyler W. ;Krause Bauer, Jeanette A. ;Connick, William B.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 360 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Fe([9] aneS 3 ) 2 ](ClO 4 ) 2 or [Fe(C 4 H 8- S 2 ) 3 ](ClO 4 ) 2 , contains an octahedral Fe II S 6 core, with the Fe atom located on an inversion center. The asymmetric unit comprises two independent half cations and two anions.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(C±C) = 0.006 A Ê Disorder in solvent or counterion R factor = 0.069 wR factor = 0.205 Data-to-parameter ratio = 14.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.008 A Ê Disorder in solvent or counterion R factor = 0.035 wR factor = 0.060 Data-to-parameter ratio = 18.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Bis(diphenylphosphino) propane-2j 2 P,P 0 0 0 -{l-2-[bis(2-mercaptoethyl)amino]ethanesulfinato(3-)-1j 4 N,S,S 0 0 0 ,S 0 0 00 0 0 :2j 2 S,S 0 0 0 }chloro-2jCl-dinitroso-1j 2 Niron(II)nickel(II) acetonitrile hemisolvate