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Bis(1,4-Diazoniabi­cyclo­[2.2.2]­octane) octamolybdate(VI) tetrahydrate

✍ Scribed by Fang, Rui-Qin ;Zhang, Xian-Ming ;Wu, Hai-Shun ;Ng, Seik Weng


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
315 KB
Volume
60
Category
Article
ISSN
1600-5368

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1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]o
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In the title compound, C~20~H~26~N~2~ ^2+^·2CF~3~SO~3~ ^−^, the dihedral angle between the phenyl rings of the dication is 9.4 (3)°. The –CF~3~ groups of both anions are disordered over two sets of positions in ratios of 0.920 (10):0.080 (10) and 0.76 (3):0.24 (3). In the crystal structure, C—H...O

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✍ Zhao, Ya-Juan ;Li, Xin-Hua ;Wang, Shun 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 255 KB

The title compound, (C 6 H 14 N 2 )[Co(H 2 O) 6 ](SO 4 ) 2 , consists of hexaaquacobalt(II) cations, 1,4-diazabicyclo[2,2,2]octane cations and sulfate anions, linked by O-HÁ Á ÁO hydrogen bonds. The geometry around the Co 2+ cation is octahedral.

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The title compound, C 6 H 14 N 2 2+ Á2NO 3 À , was synthesized under hydrothermal conditions. The asymmetric unit consists of one protonated 1,4-diazabicyclo[2.2.2]octane (DABCO) molecule and two nitrate anions. The structure is stabilized by hydrogen bonding of the nitrate O atoms to the protonated

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✍ Sun, Xian-Ming ;Qu, Yang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 312 KB

The title compound, (C 8 H 18 N 2 )[CuCl 4 ], crystallizes with two cations and two anions in the asymmetric unit. The cation was obtained by methylation of 1,4-diazabicyclo[2.2.2]octane. C-HÁ Á ÁCl hydrogen-bonding interactions link cations and anions to form an infinite three-dimensional network.