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Bis(1-benzofuro[3,2-c]pyridine-κN)dichloridocobalt(II)

✍ Scribed by Vrábel, Viktor ;Švorc, Ľubomír ;Juristová, Nadežda ;Miklovič, Jozef ;Kožíšek, Jozef

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 560 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s160053680704161x

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✦ Synopsis

In the title complex, [CoCl 2 (C 11 H 7 NO) 2 ], the Co II atom lies on a twofold rotation axis four-coordinated by two Cl atoms and two N-donor atoms from two 1-benzofuro[3,2-c]pyridine ligands, giving a slightly distorted tetrahedral coordination environment. The N/Co/N and Cl/Co/Cl planes are nearly perpendicular, with a dihedral angle of 87.1 (1) . The dihedral angle between the two benzofuropyridine ligands is 45.8 (1) . In the crystal structure, molecules are linked into a twodimensional network parallel to the ab plane by C-HÁ Á ÁCl hydrogen bonds.

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