Bis-(β-Diketones). I. Synthesis of Compounds of the Type RCOCH 2 CO-Y-COCH 2 COR 1,2
✍ Scribed by Martin, Dean F.; Shamma, Maurice; Fernelius, W. Conard
- Book ID
- 126052372
- Publisher
- American Chemical Society
- Year
- 1958
- Tongue
- English
- Weight
- 651 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0002-7863
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## Rh(TTA)(CO)(PPhs)] [5] (TTA = thenoyltrifluoroacetone) and [Rh(ACA)(CO),] [6] were published. Products of substitution reactions of CO by PPh3 and P(OPh)s in Rh@-diketone)(CO)z complexes (where @-diketone: acetylacetone, thenoyltrifluoroacetone, trifluoroacetone, benzoyltrifluoroacetone, napht
## Abstract The synthesis of chirally pure __β__‐blockers was successfully achieved __via__ hydrolytic kinetic resolution of butyl (±)‐4‐(oxiran‐2‐ylmethoxy)benzeneacetate ((±)‐**1**) and (±)‐4‐(oxiran‐2‐ylmethoxy)benzeneacetonitrile ((±)‐**2**) in the presence of bimetallic chiral [Co(salen)]‐type