Bis-thallium(I) porphyrin complexes

✍ Scribed by Jan-Ji Lai; Shahram Khademi; Edgar F. Meyer Jr; David L. Cullen; Kevin M. Smith

• Book ID: 102399776
• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 125 KB
• Volume: 05
• Category: Article
• ISSN: 1088-4246
• DOI: 10.1002/jpp.367

✦ Synopsis

Thallium(I) complexes of 2,3,7,8,12,13,17,18-octaethylporphyrin and 5,10,15,20-tetraphenylporphyrin are shown to have two thallium(I) ions per porphyrin ligand. Syntheses, spectroscopic characteristics (UV-vis, MS, NMR), chemistry, and an X-ray crystal structure of bis-thallium(I) porphyrins are presented.