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Bis-(N-methylsalicylideneiminato)dioxomolybdenum(VI)

✍ Scribed by Tsukuma, K. ;Kawaguchi, T. ;Watanabé, T.

Book ID
117859714
Publisher
International Union of Crystallography
Year
1975
Weight
296 KB
Volume
31
Category
Article
ISSN
0567-7408

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Bis(N-pyrrolidinedithiocarbamate)dioxomolybdenum(VI): synthesis, structure and reactivity
✍ Helena Teruel; Yamila C. Gorrı́n; Larry R. Falvello 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 121 KB

A new dioxodithiocarbamato compound of molybdenum(VI), MoO 2 (S 2 CNC 4 H 8 ) 2 (1), has been prepared and its reactivity towards substituted silanes, R 3 SiX (for R =Me, and X=Cl, Br, NCS, SO 3 Cl; R=n-Bu, X= Cl), HClO 4 and PPh 3 has been studied. The structure of 1 was determined by X-ray analysi