Bis- and Tris(tetraazamacrocyclic) Copper Complexes with Disulfide Linkers
✍ Scribed by Monika Galińska; Bohdan Korybut-Daszkiewicz; Urszula E. Wawrzyniak; Renata Bilewicz; Pawel Śledź; Radosław Kamiński; Paulina Dominiak; Krzysztof Woźniak
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 470 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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## Abstract Di‐ and trinuclear complexes of copper(I) bearing bis‐ or tris‐N‐heterocyclic carbene ligands have been prepared and evaluated as catalysts in nitrene transfer reactions from PhI=NTs to unsaturated and saturated substrates (olefin aziridination and C–H bond amidation) and carbene transf
The sequential reaction of two equivalents of the dimethyl-(PEt 3 ) 2 CϵCH], is described. When three equivalents of 1a are treated, first with three equivalents of nBuLi and then amino (ethynyl)carbene complexes [(CO) 5 M=C(NMe 2 )CϵCH] [M = W (1a), Cr (1b)] with two equivalents of nBuLi and one wi