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Bipositive Metal Complexes of N1 -(4-Chlorophenyl)-N4-(3,5-Dinitrobenzoyl) Thiosemicarbazide

✍ Scribed by D. K. Dwivedi; B. V. Agarwala; A. K. Dey


Book ID
101762219
Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
262 KB
Volume
96
Category
Article
ISSN
0037-9646

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πŸ“œ SIMILAR VOLUMES


The Synthesis of 3-[3-(4-chlorophenyl)-1
✍ William V. Murray πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 203 KB

Compound 2 was synthesized in 4 steps in 65% overall yield. Mechanistic studies of the key pyrazole forming step revealed a tetrahyrofuran intermediate (10) of the starting l-(4-chlorophenyl)-6-hydroxyhexane-1,8dione (3). This intermediate reverses the normal regioselectivity observed in additions