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Bipolaronic state of V4+ ion pair in the quasi-one-dimensional conductor MxV2O5 systems

✍ Scribed by Nagasawa, H.; Erata, T.; Onoda, M.; Suzuki, H.; Kanai, Y.; Kagoshima, S.

Book ID
123308835
Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
137 KB
Volume
31-34
Category
Article
ISSN
0304-8853

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A theoretical model shows that the silver ion distribution observed within the iodide tetrahedra of [(CH 3 ) 2 N(CH 2 CH 2 ) 2 O]Ag 4 I 5 is consistent with their disorder being a cooperative effect. The results indicate that the occurrence of silver ions in neighboring tetrahedra is thus eliminated