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Bi(OTf)3-catalyzed allylation of quinones with allyltrimethylsilane

โœ Scribed by J.S Yadav; B.V.S Reddy; T Swamy


Book ID
104253815
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
191 KB
Volume
44
Category
Article
ISSN
0040-4039

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Bi(OTf)3-catalyzed allylation of epoxide
โœ J.S. Yadav; B.V.S. Reddy; G. Satheesh ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 168 KB

Epoxides react smoothly with tetraallyltin in the presence of 2 mol% of Bi(OTf) 3 under mild reaction conditions to afford the corresponding homoallylic alcohols in excellent yields with high regioselectivity while aryl aziridines produce exclusively allyl amines in good yields under similar conditi