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Biosynthetic studies of marine lipids. 32. The missing step in sterol cyclopropyl biosynthesis: enzymic desaturation of 24(S)-ethylcholesterol

โœ Scribed by Giner, Jose Luis; Silva, Christopher J.; Djerassi, Carl


Book ID
127103490
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
253 KB
Volume
112
Category
Article
ISSN
0002-7863

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โœ John R. Proudfoot; C.A.N. Catalan; Carl Djerassi; D. Sica; G. Sodano ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 302 KB

Petrosterol, an unusual cyclopropane-containing marine sponge sterol, is shown, unexpectedly, to be derived by SAM biomethylation of 24-methylenaoholesterol via a complex rearrangement process.