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Biosynthesis of valine and isoleucine: synthesis and biological activity of (2S)-?-acetolactic acid (2-hydroxy-2-methyl-3-oxobutanoic acid), and (2R)- and (2S)-?-acetohydroxybutyric acid (2-ethyl-2-hydroxy-3-oxobutanoic acid)

✍ Scribed by Armstrong, Frank B.; Lipscomb, Elizabeth L.; Crout, David H. G.; Mitchell, Michael B.; Prakash, Shimoga R.

Book ID
127199506
Publisher
Royal Society of Chemistry
Year
1983
Weight
784 KB
Volume
0
Category
Article
ISSN
1472-7781

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Synthesis of (R)- and (S)-2-hydroxy-3-en
Synthesis of (R)- and (S)-2-hydroxy-3-enoic acid esters
✍ E. G. J. C. Warmerdam; A. M. C. H. van den Nieuwendijk; J. Brussee; A. van der G πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 558 KB

## Abstract The synthesis of (__R__)‐ and (__S__)‐2‐hydroxy‐3‐enoic acid esters [(__R__)‐1a‐d and (__S__)‐1a‐c] is described. The (__R__) enantiomers were prepared by a Pinner synthesis from the corresponding (__R__)‐cyanohydrins [(__R__)‐2a‐d], which in turn were obtained by R‐oxynitrilase‐ (E.C.