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Biosynthesis of the vinca alkaloids. The incorporation of geraniol-3-14C into catharanthine and vindoline

โœ Scribed by Edward Leete; Shinichi Ueda


Publisher
Elsevier Science
Year
1966
Tongue
French
Weight
139 KB
Volume
7
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Recently Battersby (l), Arlgonl (2), Scott (3), and their research teams independently dlacovered that geranlol is a precursor of the non-tryptophan derived portion of the lndole alkaloids found In Vlnca rosea . The pattern of labelllng --


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Biosynthesis of acaterin: Incorporation
โœ Yasuyo Sekiyama; Hiroshi Araya; Keiji Hasumi; Akira Endo; Yoshinori Fujimoto ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 175 KB

The biosynthesis of the lactone moiety ofacaterin was studied using Pseudomona~ sp. A92. Feeding experiment with (2R S)-[1 -I 3C]glycerol revealed that glycerol is efficiently incorporated into the branched three-carbon unit (C-3, C-4 and C-5 positions) of acaterin and its precursor, 4,5--didehydroa