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Biosynthesis of the marine cyanobacterial metabolite barbamide. 2: Elucidation of the origin of the thiazole ring by application of a new GHNMBC experiment

✍ Scribed by R.Thomas Williamson; Namthip Sitachitta; William H. Gerwick

Book ID: 104261791
Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 236 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01008-4

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✦ Synopsis

A new NMR experiment is presented for the detection of intact 13CJSN units in biosynthetic studies.

Its use is demonstrated through a feeding experiment utilizing [2J3C,15N] glyeine which confirmed the origin of the thiazole ring in the marine cyanobaeterial metabolite barbamide as originating from eysteine.

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