Biosynthesis of gallotannins: Formation of polygalloylglucoses by enzymatic acylation of 1,2,3,4,6-penta-O-galloylglucose
✍ Scribed by Andreas S. Hofmann; Georg G. Gross
- Book ID
- 115708639
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- English
- Weight
- 281 KB
- Volume
- 283
- Category
- Article
- ISSN
- 0003-9861
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Partially acetylated sucroses have been prepared by several approaches. They can be synthesized, from trityl ethers and acetals of sucrose, as precursors, by several conventional chemical methodslF3. They can also be prepared by the selective deacylation of peracetylated sucrose, in chloroform solut
## Abstract The synthesis of 1,2,3,4,6‐penta‐__O__‐galloyl‐[U‐^14^C]‐D‐glucopyranose is described. [U‐^14^C] glucopyranose was reacted with tri‐O‐benzylgallic acid forming 1,2,3,4,6‐penta(tri‐O‐benzylgalloyl)‐[U‐^14^C]‐D‐glucopyranose as chromatograpically separable anomers. Removal of the benzyl g