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Biosynthesis of epilachnene, a macrocyclic defensive alkaloid of the Mexican bean beetle

✍ Scribed by Athula B. Attygalle; Aleš Svatoš; Martin Veith; Jay J. Farmer; Jerrold Meinwald; Scott Smedley; Andrés González; Thomas Eisner


Book ID
108379187
Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
750 KB
Volume
55
Category
Article
ISSN
0040-4020

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Synthesis and absolute configuration of
✍ Xiongwei Shi; Athula B. Attygalle; Ferrold Meinwald 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 235 KB

Syntheses of (2S, 12' R)-2-( 12' -aminotridecyl)-pyrrolidine ( 1 ) and (2S, 12' R)-I -(2' '-hydroxyethyl)-2-(l 2'aminotridecyl)-pyrrolidine (2), two defensive alkaloids recently isolated from the Mexican bean beetle, Epilachna varivestis, are described. By a comparison of IH NMR data of MTPA derivat