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Biosynthesis of 5,6-dimethylbenzimidazole from [1'-14C,5-15N]6,7-dimethyl-8-ribityllumazine

✍ Scribed by Lu, Sheue-Hon; Alworth, William L.


Book ID
127137519
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
463 KB
Volume
11
Category
Article
ISSN
0006-2960

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## Abstract A novel synthesis of substituted thieno[3,2‐__c__]azepinones is described. This new approach uses 5,5‐dimethyl‐1,3‐cyclohexanedione (dimedone) as the starting material. Oxime intermediates are obtained in three steps from the aforementioned diketone. Using these intermediates, the title