## Abstract The ultrasonic degradation of poly(acrylic acid), a water‐soluble polymer, was studied in the presence of persulfates at different temperatures in binary solvent mixtures of methanol and water. The degraded samples were analyzed by gel permeation chromatography for the time evolution of
Biosynthesis and ultrasonic degradation of bacterial poly(γ-glutamic acid)
✍ Scribed by Graciela Pérez-Camero; Francisco Congregado; Jordi J. Bou; Sebastián Muñoz-Guerra
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 114 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0006-3592
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✦ Synopsis
A study of the production of poly(␥-glutamic acid) (PGGA) by Bacillus licheniformis NCIMB 11709 grown on medium E in shake flasks at 30°C is reported. The enantiomeric composition of PGGA was found to be highly sensitive to the concentration of Mn ++ , especially when the ion is present in small amounts (ഛ 20 µM). Polymers with D-unit contents ranging from 10 to 90 % and Mw between 0.4 and 2.0 million g mol -1 were obtained for [Mn ++ ] ranging from 0 to 1230 µM. Ultrasonic degradation was proven to be an effective method to reduce both the molecular weight and the polydispersity of naturally produced PGGA without disturbing the chemical constitution of the polymer.
📜 SIMILAR VOLUMES
Complex shear viscosity q\* = 7'iq" of poly(L-glutamic acid) solution was measwed by the torsional crystal method at 50 kc./sec. as a function of pH. A sharp peak was found at the midpoint of the helix-coil transition region in both q' and 7". The relaxation time is calculated from 7' and 7" assumin