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Biosynthesis and Site of Production of Sex Pheromone Components of the Cerambycid Beetle,Hedypathes betulinus

✍ Scribed by Paulo H. G. Zarbin, Marcy G. Fonseca, Daiane Szczerbowski…

Book ID
120694998
Publisher
Springer
Year
2013
Tongue
English
Weight
271 KB
Volume
39
Category
Article
ISSN
0098-0331

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Enantioselective synthesis and absolute
Enantioselective synthesis and absolute configuration of the sex pheromone of Hedypathes betulinus (Coleoptera: Cerambycidae)
✍ Diogo M. Vidal; Marcy G. Fonseca; Paulo H.G. Zarbin 📂 Article 📅 2010 🏛 Elsevier Science 🌐 French ⚖ 244 KB

The male-produced sex pheromone of Hedypathes betulinus was identified as a mixture of (E)-6,10dimethyl-5,9-undecadien-2-one (geranylacetone) (1) and its respective alcohol (2) and acetate (3). Kinetic resolution of alcohol (2) promoted by CAL-B in organic media provided both, (R)-(À)-(E)-6,10dimeth