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Biosorption of palladium and platinum by sulfate-reducing bacteria

✍ Scribed by Inmaculada de Vargas; Lynne E Macaskie; Eric Guibal


Publisher
Wiley (John Wiley & Sons)
Year
2003
Tongue
English
Weight
156 KB
Volume
79
Category
Article
ISSN
0268-2575

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✦ Synopsis


Abstract

The biosorption capacities of palladium and platinum were studied in three different species of Desulfovibrio: Desulfovibrio desulfuricans, Desulfovibrio fructosivorans and Desulfovibrio vulgaris. The influence of several parameters such as pH, acidic background and competitor anions on biosorption equilibria and biosorption kinetics were evaluated. Differences were observed between the three strains of Desulfovibrio with respect to the optimum biosorption parameters of both metals, suggesting differences in the metal speciation–dependent sorption mechanisms involved. The most promising Pd and Pt biosorption results were obtained using D desulfuricans with rapid achievement of equilibrium (90% of total sorption was achieved in 5–15 min) and a maximum value of 190 mg g^βˆ’1^ dry biomass and 90 mg g^βˆ’1^ dry biomass for Pd and Pt accumulation respectively, at pH 3. Copyright Β© 2003 Society of Chemical Industry


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Chromate reduction by immobilized pallad
✍ A.C. Humphries; I.P. Mikheenko; L.E. Macaskie πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 203 KB

## Abstract Resting cells of __Desulfovibrio vulgaris__ NCIMB 8303 and __Desulfovibrio desulfuricans__ NCIMB 8307 were used for the hydrogenase‐mediated reduction of Pd(II) to Pd(0). The resulting hybrid palladium bionanocatalyst (Bio‐Pd(0)) was used in the reduction of Cr(VI) to the less environme