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Biorthogonal analogue of the Hermite polynomials and the inversion of the fourier transform with respect to a nongaussian measure

✍ Scribed by Yu. L. Daletskii

Publisher
Springer US
Year
1991
Tongue
English
Weight
191 KB
Volume
25
Category
Article
ISSN
0016-2663

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Stereoselective transformation of amines
Stereoselective transformation of amines to alcohols enriched with the enantiomer formed by respectively inversion and retention of configuration
✍ Nina Ileby; Marek Kuzma; Lindis R. Heggvik; Karsten SΓΈrbye; Anne Fiksdahl πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 English βš– 420 KB

We hereby report the transformation of the chiral amines 1-3 to the corresponding alcohols 4-6 with 90-100% inversion of stereochemistry. KNO2 and catalytic amounts of 18-crown-6 were used in the nucleophilic attack on the N,N-ditosylimide intermediates la-3a. A diazotization reaction for the corres