✦ LIBER ✦
Biomimetic Zinc Complexes With A New Tripodal Nitrogen-Donor Ligand: Tris[2-(1-methyl-4-tolylimidazolyl)phosphane] (PimMe,pTol)
✍ Scribed by Wolfgang Kläui; Claudia Piefer; Gerd Rheinwald; Heinrich Lang
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 346 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
✦ Synopsis
The new potentially threefold-chelating ligand tris[2-(1methyl-4-tolylimidazolyl)]phosphane (Pim Me,pTol ) has been prepared. The p-tolyl substituents on the imidazole rings form a shielded hydrophobic cavity. The first X-ray-structure analysis of this ligand system confirms the proposed structure. The reaction of Pim Me,pTol with ZnX 2 salts (X = Cl,