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Biomimetic oxidation of sulfides with sodium periodate catalyzed by polystyrene-bound manganese (III) tetrapyridylporphyrin

✍ Scribed by Majid Moghadam; Shahram Tangestaninejad; Valiollah Mirkhani; Iraj Mohammadpoor-Baltork; Ali Akbar Abbasi-Larki

Book ID: 103812345
Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 357 KB
Volume: 349
Category: Article
ISSN: 0926-860X
DOI: 10.1016/j.apcata.2008.07.034

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## Abstract The oxidation of 4‐substituted phenyl phenyl sulfides was carried out with several oxo(salen)manganese(V) complexes in MeCN/H~2~O 9 : 1. The kinetic data show that the reaction is first‐order each in the oxidant and sulfide. Electron‐attracting substituents in the sulfides and electron‐