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Biomimetic oxidation of methyl 3,5-dibromo-4-hydroxyphenylpyruvate oxime and related phenols

✍ Scribed by Hitoshi Noda; Masatake Niwa; Shosuke Yamamura

Book ID
104234207
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
150 KB
Volume
22
Category
Article
ISSN
0040-4039

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4,4-Dibromo-3-methylpyrazol-5-one: New a
4,4-Dibromo-3-methylpyrazol-5-one: New applications for selective monobromination of phenols and oxidation of sulfides to sulfoxides
✍ Sabir H. Mashraqui; Chandrashekar D. Mudaliar; Harini Hariharasubrahmanian πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 210 KB

Dibromopyrazolone 1, a stable, crystalline solid effects para selective monobromination of phenols and aniline substrates under mild conditions. Selective oxidation of sulfides to sulfoxides can also be accomplished by using 1 in high yields.