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Biomimetic Hydroxylation of Nonactivated CH2 Groups with Copper Complexes and Molecular Oxygen

✍ Scribed by Bruno Schönecker; Tatjana Zheldakova; Yong Liu; Manuela Kötteritzsch; Wolfgang Günther; Helmar Görls


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
147 KB
Volume
42
Category
Article
ISSN
0044-8249

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Hydroxylation of Alkanes by Molecular Oxygen with Dinuclear Fe(II) Macrocyclic Complexes as Catalysts. -The 24-membered macrocyclic iron complex, RBP, is found to be a better catalyst for the oxidation of alkanes (I) and (IV) than the 30-membered macrocycle RBB. H 2 S acts as 2-electron reductant. -