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Biomimetic cyclization of caryophyllene to β-panasinsene

✍ Scribed by A. V. Tkachev; Zh. V. Dubovenko; V. A. Pentegova

Publisher
Springer
Year
1984
Tongue
English
Weight
189 KB
Volume
20
Category
Article
ISSN
0009-3130

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New members of the caryophyllene family
New members of the caryophyllene family via biomimetic π-cyclizations and consecutive transformations.
✍ Carsten E Sowa; Ulrike Eggert; H.Martin R Hoffmann 📂 Article 📅 1993 🏛 Elsevier Science 🌐 French ⚖ 652 KB

A series of derivatives from caryophyllene oxide have been prepared in enantiomerically pure form, including bicyclic, tricyclic and tetracyclic sesquiterpenes and sesquiterpenoids. A key intermediate is the unsaturated, chiral (pro lS,82)-bridgehead carbocation 5 and its monobrominated derivative