We report a quantitative theoretical analysis of long-range electron transfer through sensitizer wires bound in the active-site channel of cytochrome P450cam. Each sensitizer wire consists of a substrate group with high binding affinity for the enzyme active site connected to a ruthenium-diimine thr
✦ LIBER ✦
Biological electron tunneling through native protein media
✍ Scribed by C. C. Moser; C. C. Page; X. Chen; P. L. Dutton
- Book ID
- 106232846
- Publisher
- John Wiley and Sons
- Year
- 1997
- Tongue
- English
- Weight
- 151 KB
- Volume
- 2
- Category
- Article
- ISSN
- 1432-1327
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## Abstract A novel approach to acrylate/methacrylate‐based monolithic systems via electron‐beam (EB) initiated polymerization is described. The thus obtained monolithic columns were found suitable for the analytical scale separation of proteins. The novel concept of monolith synthesis was successf