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Bioinspired Nonheme Iron Catalysts for Olefin Oxidation

✍ Scribed by Paul D. Oldenburg; Lawrence Que

Publisher
John Wiley and Sons
Year
2007
Weight
18 KB
Volume
38
Category
Article
ISSN
0931-7597

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The pronounced Lewis acidity explains the exceptional activity of the title compound as catalyst for olefin epoxidations with hydrogen peroxide. The system MTO/__t__BuOH/H~2~O~2~ transforms olefins selectively and efficiently into epoxides under very mild conditions (βˆ’30 to + 60Β°C, but normally at r