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Biogenesis of spirostan sapogenins: stereochemistry of reduction of the 24,25 double bond in the biosynthesis of sarsasapogenin

✍ Scribed by A.G. González; C. Betancor; C. G Francisco; R. Hernández; J. A Salazar; E. Suárez


Publisher
Elsevier Science
Year
1977
Tongue
French
Weight
208 KB
Volume
18
Category
Article
ISSN
0040-4039

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✦ Synopsis


It is well known that reduction of the 24,25 double bond of the A24-sterols


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✍ Y. FUJIMOTO; N. SATO; T. OKUZUMI; J. YAMADA; M. MORISAKI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

Stereochemistry of the Reduction of 24-Ethyldesmosterol to Sitosterol in Tissue Cultures of Oryza sativa. -Feeding experiments of 26-13 C-and 27-13 C-labeled sterol (I) to cultured cells of O. sativa reveal that the reduction of the double bond proceeds with an anti-addition of hydrogen atoms. The