Bioaugmentation of butane-utilizing microorganisms for the in situ cometabolic treatment of 1,1-dichloroethene, 1,1-dichloroethane, and 1,1,1-trichloroethane
β Scribed by Lewis Semprini; Mark E. Dolan; Maureen A. Mathias; Gary D. Hopkins; Perry L. McCarty
- Book ID
- 116444929
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 301 KB
- Volume
- 43
- Category
- Article
- ISSN
- 1164-5563
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The kinetics of chlorine atom abstraction from the chloroethanes (EClH j 1,1,2-C2C13H3, 1, 1-CZCl2H, and 1,2-CzCl2H4 by radiolytically generated cyclohexyl radicals was studied in the liquid phase by a competitive method. The chlorine atom abstraction data were put on an absolute basis by comparing
## Abstract The reaction mechanisms for oxidation of CH~3~CCl~2~ and CCl~3~CH~2~ radicals, formed in the atmospheric degradation of CH~3~CCl~3~ have been elucidated. The primary oxidation products from these radicals are CH~3~CClO and CCl~3~CHO, respectively. Absolute rate constants for the reactio