✦ LIBER ✦

Binuclear metal complexes XVII. Vanadium(V)-copper(I) hetero-metal binuclear complexes prepared from oxovanadium(IV) complexes with quadridentate schiff bases and copper(II) halides

✍ Scribed by H. Okawa; S. Kida

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 442 KB
Volume: 23
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)94770-4

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✦ Synopsis

Vanadium-copper hetero-metal binuclear complexes L VOCuX, *CH,OH (X = Cl and Br) have been synthesized, where L denotes N,N'-bis(salicylidene)ethylenediaminate or its homologues. The complexes were characterized on the basis of elemental analyses, infrared spectra, visible spectra, and cryomagnetic measurements, and were concluded to be of binuclear structures containing a vanadium(V) and a copper ion in each molecule.