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Binuclear complexes of macrocyclic ligands. A mixed-valence copper(II)-copper(I) complex which exhibits unusual temperature-dependent behavior

โœ Scribed by Gagne, Robert R.; Koval, Carl A.; Smith, Thomas J.


Book ID
127281634
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
274 KB
Volume
99
Category
Article
ISSN
0002-7863

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Pulsed laser resonance Raman (RR) studies of mono-and bi-nuclear complexes of Cu (1) with the bridging ligand 2,3-di-(2pyridyl)quinoxaline (dpq) and triphenyl phosphine (Ph,P) are reported. Laser flash photolysis at 416 nm or 532 nm in CHCI3 solution ofthe mononuclear complex, [ (Ph,P),Cu(dpq)]' (1)